By Wu Ch.-S.

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Wang W, Ren H, Sun F et al (2012) Synthesis of porous aromatic framework with tuning porosity via ionothermal reaction. Chen Q, Luo M, Hammershøj P et al (2012) Microporous polycarbazole with high specific surface area for gas. Zhu Y, Long H, Zhang W (2013) Imine-linked porous polymer frameworks with high small gas (H2, CO2, CH4, C2H2) uptake and CO2/N2 selectivity. Chaikittisilp W, Kubo M, Moteki T et al (2011) Porous siloxane organic hybrid with ultrahigh surface area through simultaneous polymerization destruction of functionalized cubic siloxane cages.

In comparison with PAF-1, calculated BET surface areas of various poly-amine grafted PAF-1 materials dramatically decrease with values ranging between 555 and 1,014 m2 g−1. As expected, the poly-amine grafted PAF-1 materials possess significantly enhanced CO2 uptake and decreased N2 uptake capacity at low pressures and 295 K. Among those poly-amine grafted PAF-1 materials, PAF-1-CH2DETA exhibits ultrahigh binding affinity and ever largest selectivity for CO2 compared to any reported porous material.

When they are regarded as well-defined molecular clusters, MOFs could be assembled from these building units with simple geometrical shapes. Many of the most common nets are collected in a searchable database and identified by widely used RCSR symbols, which is carefully developed by Prof. au/). The reticular chemistry with the same concept of topology-based science has been successfully extended to the synthesis of COFs. According to the criteria defined by Prof. O’Keeffe, a series of two-dimensional and three-dimensional structures could be reasonably built based on the conformation of varied nodes.

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Column Handbook for Size Exclusion Chromatography by Wu Ch.-S.


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